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Condensed Matter > Statistical Mechanics

Title: Critical point for de-mixing of binary hard spheres

Abstract: We use a two-level simulation method to analyse the critical point associated with demixing of binary hard sphere mixtures. The method exploits an accurate coarse-grained model with two-body and three-body effective interactions. Using this model within the two-level methodology allows computation of properties of the full (fine-grained) mixture. The critical point is located by computing the probability distribution for the number of large particles in the grand canonical ensemble, and matching to the universal form for the $3d$ Ising universality class. The results have a strong and unexpected dependence on the size ratio between large and small particles, which is related to three-body effective interactions, and the geometry of the underlying hard sphere packings.
Comments: 11 pages
Subjects: Statistical Mechanics (cond-mat.stat-mech); Soft Condensed Matter (cond-mat.soft)
Journal reference: Phys. Rev. E 104, 044603 (2021)
DOI: 10.1103/PhysRevE.104.044603
Cite as: arXiv:2107.01160 [cond-mat.stat-mech]
  (or arXiv:2107.01160v1 [cond-mat.stat-mech] for this version)

Submission history

From: Robert Jack [view email]
[v1] Fri, 2 Jul 2021 16:01:07 GMT (2800kb,D)

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