Title: Unequal-mass, highly-spinning binary black hole mergers in the stable mass transfer formation channel

Abstract: The growing database of gravitational-wave (GW) detections with the binary black holes (BHs) merging in the distant Universe contains subtle insights into their formation scenarios. One of the puzzling properties of detected GW sources is the possible (anti)correlation between mass ratio q of BH-BH binaries and their effective spin. We use rapid binary evolution models to demonstrate that the isolated binary evolution followed by efficient tidal spin-up of stripped helium core produces a similar pattern in Xeff vs q distributions of BH-BH mergers. In our models, the progenitors of unequal BH-BH systems in the stable mass transfer formation scenario are more likely to efficiently shrink their orbits during the second Roche-lobe overflow than the binaries that evolve into nearly equal-mass component systems. This makes it easier for unequal-mass progenitors to enter the tidal spin-up regime and later merge due to GW emission. Our results are, however, sensitive to some input assumptions, especially, the stability of mass transfer and the angular momentum loss during non-conservative mass transfer. We note that mass transfer prescriptions widely adopted in rapid codes favor the formation of BH-BH merger progenitors with unequal masses and moderate separations. We compare our results with detailed stellar model grids and find reasonable agreement after appropriate calibration of the physics models. We anticipate that future detections of unequal-mass BH-BH mergers could provide valuable constraints on the role of the stable mass transfer formation channel. A significant fraction of BH-BH detections with mass ratio q in range (0.4 - 0.7) would be consistent with the mass ratio reversal scenario during the first, relatively conservative mass transfer, and a non-enhanced angular momentum loss during the second, highly non-conservative mass transfer phase.