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Condensed Matter > Soft Condensed Matter

Title: Dipolar order controls dielectric response of glass-forming liquids

Abstract: The dielectric response of liquids reflects both, reorientation of single molecular dipoles and collective modes, i.e., dipolar cross-correlations. A recent theory predicts the latter to produce an additional slow peak in the dielectric loss spectrum. Following this idea we argue that in supercooled liquids the high-frequency power law exponent of the dielectric loss $\beta$ should be correlated with the degree of dipolar order, i.e., the Kirkwood correlation factor $g_K$. This notion is confirmed for 25 supercooled liquids. While our findings support recent theoretical work the results are shown to violate the earlier Kivelson-Madden theory.
Comments: To appear in Phys. Rev. Lett
Subjects: Soft Condensed Matter (cond-mat.soft); Disordered Systems and Neural Networks (cond-mat.dis-nn)
Cite as: arXiv:2404.14277 [cond-mat.soft]
  (or arXiv:2404.14277v1 [cond-mat.soft] for this version)

Submission history

From: Till Böhmer [view email]
[v1] Mon, 22 Apr 2024 15:26:31 GMT (102kb,D)

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