Title: OCCASO V. Chemical-abundance trends with Galactocentric distance and age

Abstract: Context. Open clusters provide valuable information on stellar nucleosynthesis and the chemical evolution of the Galactic disc, as their age and distances can be measured more precisely with photometry than for field stars. Aims. Our aim is to study the chemical distribution of the Galactic disc using open clusters by analysing the existence of gradients with Galactocentric distance, azimuth or height from the plane and dependency with age. Methods. High-resolution spectra (R>60 000) of 194 stars belonging to 36 open clusters are used to determine atmospheric parameters and chemical abundances with two independent methods: equivalent widths and spectral synthesis. The sample has been complemented with 63 clusters with high-resolution spectroscopy from literature. Results. We measure local thermodynamic equilibrium abundances for 21 elements: {\alpha} (Mg, Si, Ca, and Ti), odd-Z (Na and Al), Fe-peak (Fe, Sc, V, Cr, Mn, Co, Ni, Cu, and Zn), and neutron-capture (Sr, Y, Zr, Ba, Ce, and Nd). We also provide non-local thermodynamic equilibrium abundances for elements when corrections are available. We find inner disc young clusters enhanced in [Mg/Fe] and [Si/Fe] compared to other clusters of their age. For [Ba/Fe] we report an age trend flattening for older clusters (age<2.5 Ga). The studied elements follow the expected radial gradients as a function of their nucleosynthesis groups, which are significantly steeper for the oldest systems. For the first time, we investigate the existence of an azimuthal gradient, finding some hints of its existence among the old clusters (age>2 Ga).