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Condensed Matter > Statistical Mechanics

Title: Stochastic hydrodynamic velocity field and the representation of Langevin equations

Abstract: The fluctuation-dissipation theorem, in the Kubo original formulation, is based on the decomposition of the thermal agitation forces into a dissipative contribution and a stochastically fluctuating term. This decomposition can be avoided by introducing a stochastic velocity field, with correlation properties deriving from linear response theory. Here, we adopt this field as the comprehensive hydrodynamic/fluctuational driver of the kinematic equations of motion. With this description, we show that the Langevin equations for a Brownian particle interacting with a solvent fluid become particularly simple and can be applied even in those cases in which the classical approach, based on the concept of a stochastic thermal force, displays intrinsic difficulties e.g., in the presence of the Basset force. We show that a convenient way for describing hydrodynamic/thermal fluctuations is by expressing them in the form of Extended Poisson-Kac Processes possessing prescribed correlation properties and a continuous velocity density function. We further highlight the importance of higher-order correlation functions in the description of the stochastic hydrodynamic velocity field with special reference to short-time properties of Brownian motion. We conclude by outlining some practical implications in connection with the statistical description of particle motion in confined geometries.
Comments: 36 pages, 7 figures
Subjects: Statistical Mechanics (cond-mat.stat-mech)
Cite as: arXiv:2302.11672 [cond-mat.stat-mech]
  (or arXiv:2302.11672v1 [cond-mat.stat-mech] for this version)

Submission history

From: Rainer Klages [view email]
[v1] Wed, 22 Feb 2023 22:11:33 GMT (116kb)

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