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Condensed Matter > Statistical Mechanics

Title: Beyond Linear Response: Equivalence between Thermodynamic Geometry and Optimal Transport

Abstract: A fundamental result of thermodynamic geometry is that the optimal, minimal-work protocol that drives a nonequilibrium system between two thermodynamic states in the slow-driving limit is given by a geodesic of the friction tensor, a Riemannian metric defined on control space. For overdamped dynamics in arbitrary dimensions, we demonstrate that thermodynamic geometry is equivalent to $L^2$ optimal transport geometry defined on the space of equilibrium distributions corresponding to the control parameters. We show that obtaining optimal protocols past the slow-driving or linear response regime is computationally tractable as the sum of a friction tensor geodesic and a counterdiabatic term related to the Fisher information metric. These geodesic-counterdiabatic optimal protocols are exact for parameteric harmonic potentials, reproduce the surprising non-monotonic behavior recently discovered in linearly-biased double well optimal protocols, and explain the ubiquitous discontinuous jumps observed at the beginning and end times.
Comments: Main text made more concise, two SM sections moved to Appendices. Main text has 8 pages, 2 figures; supplementary material has 6 pages, 2 figures. (PDF in v3 did not render.)
Subjects: Statistical Mechanics (cond-mat.stat-mech)
Cite as: arXiv:2404.01286 [cond-mat.stat-mech]
  (or arXiv:2404.01286v4 [cond-mat.stat-mech] for this version)

Submission history

From: Adrianne Zhong [view email]
[v1] Mon, 1 Apr 2024 17:56:28 GMT (816kb,D)
[v2] Tue, 2 Apr 2024 17:27:36 GMT (812kb,D)
[v3] Thu, 25 Apr 2024 02:31:46 GMT (808kb,D)
[v4] Fri, 26 Apr 2024 01:03:07 GMT (811kb,D)

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