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Condensed Matter > Soft Condensed Matter

Title: Anti-Coulomb interaction between charges in a dielectric medium

Abstract: The free energy of ion solvation can be decomposed into enthalpic and entropic contributions. This helps to understand the connection between the dielectric properties and the underlying forces. We present a simple linear-response model of screened charge interactions that provides an alternative understanding of solvation barriers. Moreover, it explains the ``anti-Coulomb'' interactions (attraction between like-charged ions and repulsion between opposite-charged ions) observed in both simulations and experiments. We show that this is a universal behavior associated to the non-local response function of any dielectric or metallic system.
Comments: 9 + 7 pages, 8 + 9 figures
Subjects: Soft Condensed Matter (cond-mat.soft); Chemical Physics (physics.chem-ph); Computational Physics (physics.comp-ph)
Cite as: arXiv:2404.02824 [cond-mat.soft]
  (or arXiv:2404.02824v1 [cond-mat.soft] for this version)

Submission history

From: Alec Wills [view email]
[v1] Wed, 3 Apr 2024 15:58:17 GMT (4183kb,D)

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